Nataliia Galibarenko
(2021 - until now)
Head of Mission of Ukraine to NATO, Ambassador
Georgiy Tolkachov
(2020 - 2021)
Chargé d'affaires a.i.
Oleksii Selin
(2019 - 2020)
Chargé d'affaires a.i.
Vadym Prystaiko
(2017 - 2019)
Head of Mission of Ukraine to NATO, Ambassador
Yehor Bozhok
(2015 - 2017)
Chargé d'affaires a.i.
Ihor Dolhov
(2010-2015)
Head of Mission of Ukraine to NATO, Ambassador Extraordinary and Plenipotentiary of Ukraine to the Kingdom of Belgium and the Grand Duchy of Luxembourg
Ihor Sahach
(2008-2010)
Head of Mission of Ukraine to NATO, Ambassador
Kostiantyn Morozov
(2006-2007)
Head of Mission of Ukraine to NATO
Volodymyr Khandohiy
(2000-2005)
Head of Mission of Ukraine to NATO, Ambassador Extraordinary and Plenipotentiary of Ukraine to the Kingdom of Belgium and the Grand Duchy of Luxembourg
Kostiantyn Hryschenko
(1998-2000)
Head of Mission of Ukraine to NATO, Ambassador of Ukraine to the Kingdom of Belgium and the Grand Duchy of Luxembourg. Permanent Representative to the Organization for the Prohibition of Chemical Weapons (OPCW) in The Hague
Borys Tarasyuk
(1995-1998)
Ambassador Extraordinary and Plenipotentiary of Ukraine to the Kingdom of Belgium and the Grand Duchy of Luxembourg
(1997-1998)
Head of Mission of Ukraine to NATO
Volodymyr Vasylenko
(1992-1995)
Ambassador of Ukraine to Benelux countries, representative of Ukraine to the EU and NATO